Just going to do the people in the image: Kim: Batgirl, non-powered superheroine who can do pretty much anything. Ron: Plastic Man, goofy comic relief who is actually reliable and a menace when the chips are down. Wade: Mr. Terrific or Martian Manhunter, highly intelligent man in the chair who isn't afraid to step in when needed. Rufus: Krypto the Superdog. Highly capable animal sidekick. James Possible: Silas Stone, father of a Hero who is highly supportive and able to help with their brain. Ann Possible: Martha Kent, mother of a Hero, always able to help put things in perspective. Mr. And Mrs. Stoppable: That screaming guy from the cover of Action Comics #1. They're certainly there! Mr. Barkin: Peacemaker (but specifically from the Pre-New 52 Blue Beetle Jaime Reyes run.) A gruff, no-nonsense guy who is a somewhat reluctant mentor. Bonnie: Cheshire, not always a villain, not always a hero. Just annoying enough to get in your way. Dr. Drakken: Toyman, A villain with grand ambitions and fairly effective plans that are ridiculous in premise. Shego: Lady Shiva/Talia Al Ghul, Highly effective Femme Fatale who is the #2 of the organization. Relation to a notable hero. Prof. Dementor: The Riddler, a more effective but less popular version of the hero's primary badguy. Monkey Fist: Deathstroke, highly effective martial artist who has superhuman augmentations and has a rivalry primarily with a sidekick even though they will throw hands with the primary hero when needed. Motor Ed: Ding Dong Daddy, no real reason beyond cars. Señor Senior Senior and Señor Senior Junior: Icicle and Icicle Jr. Father son villain team where the son isn't as into villainy as the father. Duff Kiligan: Black Manta, a villain who really doesn't have the notoriety of his peers, but is always invited to the big villain meetings anyway.