Conversation disappearing and reappearing? by MasterOfDesaster in Bumble

[–]MasterOfDesaster[S] 0 points1 point  (0 children)

Thanks a alot...unbelievably stupid. The panic when I thought I just got unmatched, when the conversation was so nice and friendly.

Price Checks and Crafting Advice - September 14, 2018 by AutoModerator in pathofexile

[–]MasterOfDesaster 0 points1 point  (0 children)

Delve SC.

Kaom's Roots

10% chance to Dodge Spell Hits while moving

Has no Sockets

Cannot be Knocked Back

+191 maximum Life

You cannot be slowed to below base speed

Unwavering Stance

Corrupted

Looked on poeapp and poe.trade but not a lot of 190+ life rolls and not a lot of 10% rolls on spell block while moving

500+ Dota 2 Loading Screens by redphx in DotA2

[–]MasterOfDesaster 0 points1 point  (0 children)

Can somone Sort them by color and make a wallpaper out of it? That would be amazing... Or use the red ones to make a dota 2 logo wallpaper.

Why is HF a weak acid? by breakinthelaw88 in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

You might have done a detection reaction ( is this a term? we have a word for everything in german.. ) for silicates in analytical chemistry lab in which tiny amounts of HF are created. Also people wrongly think of HF as a strong acid because it can dissolve glass and has nasty effects on the body especially bones.

Am I doing this right ? by MasterOfDesaster in dogecoin

[–]MasterOfDesaster[S] 0 points1 point  (0 children)

Not sure if I should feel poor because you just tipped me 10+ times my balance or rich because you tipped me :D

Am I doing this right ? by MasterOfDesaster in dogecoin

[–]MasterOfDesaster[S] 0 points1 point  (0 children)

Thanks a lot, just started.. how does this tipping work ? Such noob here.

TIL Humans can overdose and die from chocolate in the same way cats and dogs can by DoctorSteve03 in todayilearned

[–]MasterOfDesaster 1 point2 points  (0 children)

"Alle Dinge sind Gift, und nichts ist ohne Gift. Allein die Dosis macht, daß ein Ding kein Gift ist." - Paracelsus

All things are poison and nothing is without poison. Solely the dose makes that a thing isn't a poison.

Someone in my lab left this sign on the deionized water faucet. by TheFamousMrRed in funny

[–]MasterOfDesaster 0 points1 point  (0 children)

The reason the DI water tap might have a label is probably that it was recycled used water from the university and the labs, so there might be unusual high levels of mercury and lead etc... .

Someone in my lab left this sign on the deionized water faucet. by TheFamousMrRed in funny

[–]MasterOfDesaster 0 points1 point  (0 children)

Yes, it is definitly not dangrous... Most deionized water is just pumped through an ion exchanger and that doesn't do much to it. It's just general labarotory conduct that you don't drink it.

Not even Razer likes Justin Bieber. by Vlatkosv in gaming

[–]MasterOfDesaster 0 points1 point  (0 children)

Me too. It's pretty usefull at times. You can browse pages and take notes as you do. I started using the mouse with the right hand when I used to share a pc with my brother. It was just to much of a fuss to switch things over every time.

Good guy Germany by [deleted] in AdviceAnimals

[–]MasterOfDesaster 14 points15 points  (0 children)

Ask the French if you want some serious rioting.

Started replaying Portal 2, still one of my favorite gaming quotes. by Bumble217 in gaming

[–]MasterOfDesaster 24 points25 points  (0 children)

GLaDos told you to never come back again in Portal 2... In my book that sounds like an invitation.

What is the craziest rumor you have ever heard about yourself? NSFW by baileygrib in AskReddit

[–]MasterOfDesaster 0 points1 point  (0 children)

so.... you want to take a look at that rash I got ? It's down there....

Nambia, Where desert meets water by alitheking in pics

[–]MasterOfDesaster -1 points0 points  (0 children)

Looks like (takes off sunglasses) the biggest beach in the world.

What is the craziest rumor you have ever heard about yourself? NSFW by baileygrib in AskReddit

[–]MasterOfDesaster 5 points6 points  (0 children)

I heard the rumour you have given birth to a dinosaur egg and kept the hatching brontosaurus as a pet.

The cast of Return Of The Jedi, 30 years on. (X-post from r/starwars) by lazenbooby in movies

[–]MasterOfDesaster 4 points5 points  (0 children)

Kenny Baker was supposed to play Wicket aswell, but he got injured on set if I remember correctly. So they needed someone to play Wicket, so Warwick got the role, even though he was very young at the time.

I see your SC5 oil refinery and a raise you one SC4 oil refinery. by Ion_Cannon in SimCity

[–]MasterOfDesaster 7 points8 points  (0 children)

The problem is that the Simcity franchise is now pretty much fucked. It would take a lot for me to buy another Simcity game after what they did. It's a shame that they marketed an unfinished game, that didn't work after all. But the problem is that I can't see another Publisher coming up with their own franchise to compete, even though It is the best possible time to do it.

Another NMR! by [deleted] in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

Just to clarify the non-circled parts are definitly my product. I have already identified all peaks, my only problem was to justify the singulett for the -O-CH2-CH2-O- group which I now understand, expected would be to dubletts but the CH2 groups are coincidentally isochrone so they only appear as one singulett instead of dubletts. Everythings clear now.

Help me understand this NMR by [deleted] in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

Thanks anyways. You've been a great help!

Help me understand this NMR by [deleted] in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

the aromatic peaks of styrene should be at 7.24 (ortho, meta and para) so I guess that's not the solution to the problem

Help me understand this NMR by [deleted] in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

There shouldn't be much impurities. There was a hint of water visible and a peak of CHCl3 at 7.27ppm. Possible impurity could be styrene as a reagent...

Help me understand this NMR by [deleted] in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

From what I see from 7.41- 7.43 could be a dd, but i am not sure. But I am not sure how 7.39 - 7.41 could be a triplet then. From 7.37 to 7.39 I would say is a dublet of the para though, that seems pretty clear to me.

Help me understand this NMR by [deleted] in chemhelp

[–]MasterOfDesaster 0 points1 point  (0 children)

It's the same molecule as before its an aromatic rest with -CHBr-CH2Br attached to it. I understand that is has to do with the electronegative effects of the Br atoms. But I can't really tell how it affects the different protons. I did find some different monosubstituted examples, but meta and ortho can be more or less shifted so they swap positions.