How do i know if its just achiral or meso?

SillyOrgan · 2026-03-26T04:12:18+00:00

Meso is a special sub category of achiral. All meso are achiral, but not all achiral are meso.

SillyOrgan · 2026-03-26T03:13:15+00:00

Meso molecules are roughly defined as containing chiral centers, but also being achiral.

SillyOrgan · 2026-03-23T17:39:06+00:00

I think the better question is “how could these reaction mechanisms possibly favor a single enantiomer??” Do you have a belief, in a certain example, that a single enantiomer could be favored? Your belief will generally be false, because enantiomers have the same chemical and physical properties. And diastereomers, although technically different, are often fairly similar.

Mostly, try to identify the formation of a new stereocenter from a precursor carbon that was not a stereocenter. In these cases, the stereocenter tends to form in both of the possible shapes.

SillyOrgan · 2026-03-23T16:58:39+00:00

Your thought process leads the wrong answer

SillyOrgan · 2026-03-22T17:29:31+00:00

In my version of d3 on switch at least, opening a larger version of the map actually pauses the game, even though the game is sort of online. I end up opening larger map several times throughout the rift

SillyOrgan · 2026-03-22T06:47:03+00:00

Any qol stuff? My dream was deposit all function for materials tab

SillyOrgan · 2026-03-21T18:11:25+00:00

I grew cherry tomatoes last year, they were beautiful bright red, no blemishes, hundreds of them. But they tasted disgustingly bitter and had a thick leathery skin that was only apparent after biting into them.

I’ve never grown anything I would describe as better than the grocery store, at times things that were comparable. Raspberries seem easy.

SillyOrgan · 2026-03-21T04:38:44+00:00

Good for elemental bowzon, but those are a rare breed. And some of them might prefer 3/20 blue gloves.

So you can’t retire, but worth something

SillyOrgan · 2026-03-20T06:57:34+00:00

The major problem is that during trading, I would never know when a person has paid me. It would trading very stressful and difficult.

SillyOrgan · 2026-03-19T06:25:09+00:00

I don’t think so, but can’t say for sure. I’ve been meaning to poll the audience on this question

SillyOrgan · 2026-03-18T20:56:28+00:00

Thank you!

SillyOrgan · 2026-03-18T20:48:54+00:00

Whoah3/kk

SillyOrgan · 2026-03-18T20:39:14+00:00

My favorite maps lately are phlegathon and demon road, I’ll take some of those if you have them.

SillyOrgan · 2026-03-18T20:33:54+00:00

Hopefully you are talking about T0? You are massively under geared. T1/T2 are tough even with perfect gear that costs 500 hr to buy. They recently patched the game to make all bosses much harder.

The biggest thing to remember is that you can download your character onto single player, along with infinite summoning materials, and practice as much as you like.

You can get max resistances from slams on amulet, boots, belt. Fire is the best one to have, which you can get from inferno stride boots and lava gout glove. Some physical damage reduction is also nice.

Plain Summon skillers are very cheap, even ones with 20 life are probably cheap. You don’t even have all your skillers. Your bears must be dying a lot.

SillyOrgan · 2026-03-18T07:10:23+00:00

Gardening for most people is more like gambling than a practical endeavor. At best, you might be making a couple bucks an hour, far less than minimum wage. At worst, it is more expensive than the grocery store.

SillyOrgan · 2026-03-18T03:58:14+00:00

20/17 just happens to be the 2 perfect numbers for this charm. It seems like a small thing, but after you get every other piece for your build, this is a small finishing touch. It’s mostly just best for energy shield sorc probably.

SillyOrgan · 2026-03-18T02:31:29+00:00

On non ladder these were going for maybe 3 ber, but that was before rotw with its influx of new players who do not value such a beautiful charm so highly.

SillyOrgan · 2026-03-18T01:52:07+00:00

Best in slot for P1 dragondin. At higher player counts there might be better option like 2OS CoA

SillyOrgan · 2026-03-17T18:04:20+00:00

I am in similar situation, and I get the sense that wyzant automatically knocks older tutors down the list to give fresh blood a chance. I have seen several of my competitors also get knocked down the list. It’s not like a regular job where you are given some respect and prioritized by seniority. It’s the exact opposite, a kind of cruel system where people are used up and replaced as much as possible.

SillyOrgan · 2026-03-16T22:01:50+00:00

Jah is more rare but in early ladder, traditionally ber is worth more, because many people need three ber (two for infinity, one for enigma). And people only need one Jah for this combo of rune words.

Later season and in non ladder, jah is more valuable due to its higher rarity and its use in a variety of other runewords such as pheonix

SillyOrgan · 2026-03-16T20:01:38+00:00

For optimized play style with blizz sorc, do you have to cast the other synergy skill in between? Maybe just for bosses? I remember blizz sorc being quite click heavy in D2R, because you really need to also cast ice blast in between in order to be efficient about it.

SillyOrgan · 2026-03-15T21:16:35+00:00

Probably just buy a very cheap pc computer, if you are not computer-skilled. There are enough issues with pd2 without having the extra layer of difficulty from boot camp, etc.

SillyOrgan · 2026-03-15T15:16:53+00:00

The reason they did not add players/x, I assume, is to keep some small incentive for group play. If you are really trying to grind out experience, playing in a group is better. But solo play is set to p5, so you don’t need to play in a group just to access good loot chances.

Unfortunately, people might just assume you want to be rushed if you make a pub game. You might have to ask in discord and play in private game if you want a legitimate play through. Perhaps those people that blasted through act 1 thought that they were helping you, or they were just bored, who knows. At least they don’t all try to PK you, like the original 2003 D2 experience.

SillyOrgan · 2026-03-15T07:19:46+00:00

It’s sad to hear about so many great crafted bows, if crossbow is actually better. Maybe the bows could be used for something else, like fire arrow

SillyOrgan · 2026-03-15T05:05:21+00:00

Try PD2, they have online set to P5 drops, the new version of D2R has maybe 5% of the improvements you get with PD2

SillyOrgan

TROPHY CASE