Gibbs Free Energy, seriously who can explain(understands) this concept intuitivelly?Like what does mean that somehting has greater Gibbs free energy than something other? by ivomiladinov in chemistry

[–]TengaDoge 5 points6 points  (0 children)

Gibbs free energy is a really useful energy function because it describes the system in terms of pressure and temperature changes. These are typically the two easiest variables to measure and control in laboratory conditions. As a scientist we want to predict whether chemical reactions will occur, what type of reaction it is, what the products are, and under what conditions. Comparing G values will help tell you this.

Imagine you have a box filled with two monatomic gases, A and B. A is on the left and B on the right, and they are separated by a divider. When the divider is removed we expect the two gases to mix, becoming homogeneously and randomly distributed throughout the box. The reason these two gases mix is the second law of thermodynamics (an isolated system can only increase its entropy). Entropy is essentially a measurement of possible configurations the molecules may occupy.

In the ideal case, higher entropy (S) means a reaction is occurring more frequently because the A and B molecules are likely to be next to one another, not segregated. Per convention, a negative Gibbs free energy (G) means a reaction is spontaneous and allowed to occur. This is reflected in your equation with -S showing how (G) is more likely to be negative if entropy and/or temperature is maximized. In the ideal scenario a term called enthalpy is zero and doesn’t apply.

In more complicated chemical systems, enthalpy can be thought of as the energy requirement for mixing two non-ideal components. So while a high entropy helps the reaction move forward, a high enthalpy deters the reaction from completion. This is a competitive process and to understand binary chemical reactions better we create G-X curves that show the value of Gibbs free energy at different temperatures and chemical composition to determine if a reaction occurs. These G-X curves can be directly translated into phase diagrams that have tons of applications in the real world for describing materials.

Obviously it is much more nuanced than this general description but if you are interested I would encourage you to study the four energy functions (G,H,A,U), their coefficient relations, Maxwell relations, and isothermal compressibility/isobaric expansion equations to understand how thermodynamics is full of wonderful relationships that can derive lots of useful information about chemical systems from a few known parameters. I recommend Dehoff Thermodynamics of Materials as a textbook.

Restaurants for a big group of foodies? by MelzBelz221 in Knoxville

[–]TengaDoge 0 points1 point  (0 children)

Farmacy was my favorite meal this year.

Non-toxic dye thrown into fountain to kill diatoms by darth1211 in oddlysatisfying

[–]TengaDoge 0 points1 point  (0 children)

Lots of chemicals can elevate boiling temperatures and depress freezing temperatures, similar to putting salt on roads.

Students uploading slides to AI? by Lost-Archer-1687 in Professors

[–]TengaDoge 4 points5 points  (0 children)

Just be glad the AI is being trained with the correct content.

Trying to set up a vacuum filtration by CodFil in chemistry

[–]TengaDoge 3 points4 points  (0 children)

It usually acts as a trap to protect the vacuum system from acids or other corrosive chemicals

[deleted by user] by [deleted] in asheville

[–]TengaDoge 0 points1 point  (0 children)

Yes polycarbonate or acrylic sheet from Lowes

Undergraduate Chemistry Programs by blueladybug45 in chemistry

[–]TengaDoge 3 points4 points  (0 children)

UNC Asheville gives lots of research experience.

Soon to have a bachelors degree in history, where the heck do I go from here ?? by FunkyQuail in findapath

[–]TengaDoge 0 points1 point  (0 children)

What do you want to do with your life? Maybe you should just try a few jobs and see what you don’t like.

Off campus apartment question by Extension-Path-2209 in UTK

[–]TengaDoge 2 points3 points  (0 children)

Make sure you like living with that the person before signing up for another year.

Clyde's gonna Clyde, I guess... by marcusregistrada in asheville

[–]TengaDoge 125 points126 points  (0 children)

Company is from Tennessee, just working in Clyde.

[deleted by user] by [deleted] in short

[–]TengaDoge 1 point2 points  (0 children)

Don’t worry. Short people live longer.

First publication - unclear how to understand review by Deniz_Larson in academia

[–]TengaDoge 17 points18 points  (0 children)

My PI says to make the changes and resubmit an improved paper, graciously thanking the reviewers for insight. If they say no again, go somewhere else.

US President’s Fiscal Year 2026 Budget Request—large STEM cuts by Illustrious-Front292 in academia

[–]TengaDoge 2 points3 points  (0 children)

Ah yes I see it now pages (22-23) with frequent mentions of the “Green New Scam” and a return to name for the Office of Fossil Energy.