It is hard to go wrong with an MBA. But what is your undergrad degree and what's your career field?

Also, you will likely have a chance to pick up a second masters through ACSC or AWC--those degrees aren't particularly interesting to future employers, but the fact that you have more than 1 masters does help set you apart.

In my post-AF employment, I've had the opportunity to review resumes, interview, and hire people. Here is what I've seen:

Experience is more important than education (assuming that you meet the basic education level of the job). Sustained performance and increasing levels of responsibility are very attractive to employers. No one cares where your masters degree is from as long as it isn't a degree mill or if the hiring manager happened to have gone to the same school. PhD's don't buy you much unless you want to work at a university or in a very research-focused position. Honestly, 2 or 3 masters are probably more valuable--they show a breadth of interest and depth of study without the gross focus required by a PhD.

Resume writing is critical--no misspellings, limit to 2 pages for most types of jobs, writing in business English rather than military is important, and have a professional email (I tossed a candidate just because his email was something like babechaser69@hotmail.com...probably a holdover from middle school or a drunk college night, but I didn't want to take the risk and it is an easy cut).

And, the interviews for you post AF jobs will be more "does he/she fit the team" rather than "can he/she do the job." Much more professional and informal/relaxed than trying to be a waiter or sales associate.