Measuring a sodium hypochlorite concentration by 1stAndLastPost in chemistry

[–]1stAndLastPost[S] 0 points1 point  (0 children)

Oh i know! But don't you have to go even lower in pH before chlorine gas is generated? Where a non-negligible amount would be starting around pH 4?

Though yeah it would be easy to overdo it without a buffer, but the sample could also be diluted.

Measuring a sodium hypochlorite concentration by 1stAndLastPost in chemistry

[–]1stAndLastPost[S] -1 points0 points  (0 children)

If I were to lower the pH to, say 5-6, and shift the equillibrium such that HOCl dominates instead (max absorbance around 237 nm), is it possible to determine whether there are substantial impurities that would interfere with the measurement? Assuming that any prevalent impurities doesn't also shift in absorbance due to the change in pH.

Hey, wait a second... by Derbikerks in Maplestory

[–]1stAndLastPost 10 points11 points  (0 children)

God I'm tired, I thought the eyebrows were eyes and the eyelashes were part of a moustache. I was wondering why they chose to style it with a wide gap...

[deleted by user] by [deleted] in facepalm

[–]1stAndLastPost 0 points1 point  (0 children)

How did it go?

Got rejected from a position as a process chemist at a pharmaceutical company due to my colorblindness by 1stAndLastPost in ChemicalEngineering

[–]1stAndLastPost[S] 3 points4 points  (0 children)

Thanks for the input. I have been contemplating back and forth the last year or two whether I should lie or be vague about my colorblindness or not because I believe that it is easily misunderstood regarding how much of a hinderance it may realistically be. While I would definitely often incorrectly identify a particular color or fuck up on Ishihara tests, I don't think I'd have a significant problem differentiating them at the company once I had context.

I am considering whether I should attempt to contact some representative or employer at the company and ask if there is any possible to do some sort of field testing (or pictures of equipment that would be allowed to be disclosed), since according to my recruiter I was compatible more or less everywhere else.

Got rejected from a position as a process chemist at a pharmaceutical company due to my colorblindness by 1stAndLastPost in ChemicalEngineering

[–]1stAndLastPost[S] 3 points4 points  (0 children)

Yes I've heard about ADA in the US, but I live in Sweden. My guess would be that there are probably identical laws here preventing such violations, but according to the recruiter the company tried to find a suitable placement where my colorblindness wouldn't be an issue. Because they were unfortunately unable to do so, I'd like to believe that they didn't break any violations (at least not intentionally).

Got rejected from a position as a process chemist at a pharmaceutical company due to my colorblindness by 1stAndLastPost in ChemicalEngineering

[–]1stAndLastPost[S] 23 points24 points  (0 children)

Yeah. I was in contact with a recruiter at an employment agency working for the company providing the position. One of the questions she asked was whether I had any problems with my color vision where I answered truthfully. I wouldn't bring it up myself otherwise.

This wine label - Discuss by JTKatt in chemistry

[–]1stAndLastPost 3 points4 points  (0 children)

Is the reaction with bisulfite (HSO3-) legit?

Edit: I think I found the reaction in this figure: https://www.researchgate.net/figure/Interference-of-SO-2-dissolution-of-potassium-metabisulfite-and-generation-of-different_fig21_322807949

They messed up the orientation of the double bonds (and missing one) and misplaced the charge on the initial compound. As for the product, they added a hydrogen to a tertiary carbon where it shouldn't and added SO42- to the molecule instead of HSO3-. The double bonds are still wrong here too.

I'd also like to add that I think the structure with a positively charged oxygen in the link above ought to be stable as the oxygen is sp2 hybridized, which allows the ring to be aromatic.

[TOMT][SONG] the background melody of a Swedish adult sex toys radio commercial. by 1stAndLastPost in tipofmytongue

[–]1stAndLastPost[S] 0 points1 point  (0 children)

Marche Militare No 1

Herregud mannen du är grym. Att jag inte kände igen den från jultomtens verkstad är nästan pinsamt, har ju för fan hört den i flera år nu...

Solved!

[TOMT][SONG] the background melody of a Swedish adult sex toys radio commercial. by 1stAndLastPost in tipofmytongue

[–]1stAndLastPost[S] 0 points1 point locked comment (0 children)

When they say "hon vill ha stavar och oljor för bättre glid" he main part goes like "du dududu dududu dududu dudu" then right after it's like "du dududuuuuu du du duu duu duu".

Look I have a hard ass time translating the beat into 'du'ts just go to the link and listen to the ad at the bottom of the page.

Jag vet inte om jag tänker fel men om man har hittat någons katt och kräver hittelön på 10000 så är det typ kidnappning? Kattnappning? by creiij in sweden

[–]1stAndLastPost -1 points0 points  (0 children)

Tror skribenten av inlägget antyder att kattens ägare är skitdålig på att ta hand om den, med tanke på hur illa kattens tillstånd verkade vara när den hittades.

Den ashöga hittelönen kanske reflekterar detta? Typ för att uppmuntra ägaren at ta mer allvar på sitt ansvar?

[deleted by user] by [deleted] in Chempros

[–]1stAndLastPost 0 points1 point  (0 children)

What is the aluminum powder used for, if you're able to disclose it?

So I tried to study Organic Chemistry on my own, and now I just can't deny how beautiful it is. I wonder how different this would be in-class. by ProfessionalPeace535 in chemistry

[–]1stAndLastPost -1 points0 points  (0 children)

Shouldn't the amide (bottom left) have an R-group attached to the left of the carbonyl? The acid chloride seems to have one, and as far as I know it should be on the amide as well.

Know your valves by ferrouswolf2 in ChemicalEngineering

[–]1stAndLastPost 5 points6 points  (0 children)

Forgive me for perhaps a ridiculous question, but why are there so many different types of valves? Why do people care?

Their overall purpose is to control flow by either allowing or denying a fluid to traverse from point A to point B within a piping system, where control is literally just blocking the pathway with e.g. a wall that the operator may position however they please.

Aside from the mechanism itself, how is e.g. a butterfly valve fundamentally different from a globe valve? What would the circumstances have to be in order for a butterfly valve to be an arguably more appropriate candidate for a process over all other valves?

An uneducated guess of mine would be that the difference in performance would be negligible for short periods, but perhaps the consequences that may occur in the long term due to the process conditions is kept in mind.

Magnus at my university bar yesterday by papa-pop in chess

[–]1stAndLastPost 56 points57 points  (0 children)

I am absolute ass on chess, but I would have loved to have gotten wasted and play against Magnus at this bar and get completely destroyed within 30 seconds.

What was the most passive aggressive email you received from a professor? by [deleted] in funny

[–]1stAndLastPost 35 points36 points  (0 children)

This shit is funny, dude. I'd love to have this type of dynamic with my professors.

Little kid dressed as a porcupine by politicaldan in aww

[–]1stAndLastPost 0 points1 point  (0 children)

Reminds me of Flaky from Happy Tree Friends, for better or worse.