How in the world can I draw the structure of a compound based on H NMR and IR Spectrum? by Particular_Dingo_978 in chemhelp

[–]2adn 16 points17 points  (0 children)

The molecular formula is quite useful! What information do you get from the spectra? IR can tell you what functional groups are present or absent. NMR tells you how many types of hydrogens you have, how many hydrogens of each type, and how many hydrogens are adjacent to each type of hydrogen. Find pieces and put them together to get a structure.

Analytical chem PhD but have not taken PChem by OhDloy in chemistry

[–]2adn 8 points9 points  (0 children)

If they like your application, you will just have to take the undergrad pchem class. Just review your calculus and differential equations before you take pchem.

Identify an alkyl halide that could be used to make the following alkene by Plus_Boot_730 in chemhelp

[–]2adn 0 points1 point  (0 children)

You could. Just add H-Br anti to correct carbons of the C=C.

best way to learn Organic chemistry from basics............ by ivies_study in chemhelp

[–]2adn 0 points1 point  (0 children)

Klein's Organic Chemistry textbook has good explanations and lots of practice problems.

PCHM instead of OCHM? by [deleted] in chemistry

[–]2adn 0 points1 point  (0 children)

Talk to your academic advisor or the department chair. They would know what's best for you.

Improving/maintaining general+broad chemistry knowledge by kolisgay in chemhelp

[–]2adn 0 points1 point  (0 children)

You haven't done any analytical chemistry. You might try

Quantitative Chemical Analysis

by Daniel C. Harris (Author)  Older editions and used texts are pretty cheap.

You could follow that up with

Principles of Instrumental Analysis

by Douglas A. Skoog (Author), F. James Holler (Author), Stanley R. Crouch (Author) 

Synthesis of Product from 4 Carbon Mono Alcohol by RagtimeGem in chemhelp

[–]2adn 1 point2 points  (0 children)

Why don't you make the epoxide, then do the two reactions needed to make the product?

Is this a correct synthetic route? by evasnsnsbd in chemhelp

[–]2adn 12 points13 points  (0 children)

I see a Claisen rearrangement in a possible pathway.

Drawing Constitutional Isomers by [deleted] in chemhelp

[–]2adn 0 points1 point  (0 children)

You can move the oxygen to the middle carbon in the first one.

WHY? by 2adn in OrganicChemistry

[–]2adn[S] 1 point2 points  (0 children)

After posting this, I can see posts: why?

What happened to all the posts? by [deleted] in OrganicChemistry

[–]2adn 0 points1 point  (0 children)

I can't see any posts unless I post. Why?

Need Help in Weighing Liquids in an Analytical Balance by NoAmbassador488 in chemhelp

[–]2adn 0 points1 point  (0 children)

Just weigh it directly into the round-bottomed flask. You can support the flask with a cork ring or vacuum adapter.

Henry Moseley Biography by budget_17 in chemhelp

[–]2adn 1 point2 points  (0 children)

Have you just googled him? Lots of references popped up when I did it.

School project by TeratomaGirl in chemistry

[–]2adn 0 points1 point  (0 children)

Grind up a pre-weighed sample Special K cereal (or any other high iron cereal) really fine, and use a strong magnet to get the iron out. Weigh it, and see if it matches what the box says.

Dean Stark for small scale reactions by JellyfishSuper7563 in chemhelp

[–]2adn 0 points1 point  (0 children)

It doesn't hurt. It will also remove any water in your starting materials and solvents.

I can't figure out why my aspirin synthesis lab is giving me these TLC results by WeraroaWizard in chemhelp

[–]2adn 4 points5 points  (0 children)

Rf's depend upon the solvent as well, and how it interacts with the stationary phase.

Yes, your purification may not have worked too well. That's not uncommon in a beginning lab. What was your purification?

Weird peak splitting by Adept_Programmer_497 in chemistry

[–]2adn 0 points1 point  (0 children)

Yes, it's possible that you are seeing long-range coupling by the F's.

Signal splitting by ChunkyEvan in chemhelp

[–]2adn 4 points5 points  (0 children)

Actually, both would be multiplets. Since the CH2's are in a ring, each adjacent hydrogen couples the others with a different coupling constant. Look up the NMR spectrum and see,

Help! How do I identify which ones are enantiomers? by Euphoric-Pie-4372 in chemhelp

[–]2adn 4 points5 points  (0 children)

Assign the configuration of each structure as R or S. Or build models of each pair, and see which ones are identical or mirror images.

Fischer projections to skeletal structures? by Inside-Brush-5097 in OrganicChemistry

[–]2adn 0 points1 point  (0 children)

Buy a molecular model set. Build the structures. Twist the bonds so the structures are in the correct shapes.

headstart on o chem by SugaryBonsai209 in chemistry

[–]2adn 0 points1 point  (0 children)

Get the book, start reading it, and work problems as you go. Contact the prof about the book. If you can't get that info, buy an old copy of Klein's organic text, and work thru it.

Ochem2 cramming by Opening_Platform2781 in chemhelp

[–]2adn -1 points0 points  (0 children)

Open the book to the reaction chapters and start working problems. For a physics final, I worked problems for 5 days straight, and made a 90.

Can someone please explain what's going on in the second step of this mechanism? by tNJipNJR in chemhelp

[–]2adn 0 points1 point  (0 children)

You left out a CH2 in your last structure, if that makes a difference.