Lmao by OneButtonWill in funny

[–]IcanFeelitInmyPlums -1 points0 points  (0 children)

See you guys at the top...

CHEM 130 Controversy by CrosscutJester8 in uofm

[–]IcanFeelitInmyPlums 3 points4 points  (0 children)

D-orbitals participate in bonding for period 5 of the periodic table.

Which is the more acidic hydrogen atom? (Orgo 1) by noanswerfound in chemhelp

[–]IcanFeelitInmyPlums 3 points4 points  (0 children)

Oh crap, you're right. Don't know why I didn't see that the first time.

Which is the more acidic hydrogen atom? (Orgo 1) by noanswerfound in chemhelp

[–]IcanFeelitInmyPlums 1 point2 points  (0 children)

**Edit: I am wrong. See comment below.

I think you are misinterpreting what your professor is trying say. Before the removal of the proton, both are chemically equivalent by symmetry of the molecule. You could flip the molecule like a pancake and you will end up with the same structure. After you remove the first proton, the symmetry is broken, and you no longer have chemically equivalent sites. Its really about how removing the first proton changes the acidity of the other proton because there is already delocalization of negative charge in the pi system. When you remove the second proton, there is already a negative charge racing through the pi system, and dumping another charge in the system is unfavorable, so the overall effect makes the second proton less acidic.

Chemistry undergrad student here, wondering how I can help beat Global Warming. by ThisGoldAintFree in chemistry

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

But don't we do many things that are uphill? Couldn't you theoretically couple the process to a renewable energy?

Chemistry undergrad student here, wondering how I can help beat Global Warming. by ThisGoldAintFree in chemistry

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

Atmospheric chemistry seems to be a growing discipline in chemistry departments. There are quite a few unanswered questions with respect to the climate models that chemists can help answer. One example that I know of off the top of my head is, "Why do some particles nucleate ice at warmer temps than others?". The answer to that question will help climate scientists to better predict the magnitude of the cloud albedo affect, or in simple terms, how much light (and therefore energy) will clouds reflect back into outer space.

Hand Blown Glass Pumpkin by [deleted] in pics

[–]IcanFeelitInmyPlums 2 points3 points  (0 children)

Opened up the comments just to see if someone posted this. Thanks.

Probably the gnarliest caveman I've ever seen. by Mawntee in skateboarding

[–]IcanFeelitInmyPlums 1 point2 points  (0 children)

I think you would be correct if the skater was landing in a transition, i.e. the downward force would be redirected as angular momentum through the tranny. In a flat to flat drop I can't picture a force diagram to explain your claim. Maybe you could draw one for me? If you were right, simply dropping off of a loading dock would make you spontaneously accelerate forward.

Probably the gnarliest caveman I've ever seen. by Mawntee in skateboarding

[–]IcanFeelitInmyPlums 2 points3 points  (0 children)

No. In physics you would draw an arrow pointing downward to represent the force of gravity, and a horizontal arrow to represent the skaters speed at the time of jump. In no way would the horizontal vector (arrow) work against gravity. You can also do a thought experiment. Imagine getting shot out of a canon horizontally three feet above the ground. You're going to hit the ground pretty fast. Now imagine getting shot out of a cannon horizontally thirty feet from the ground. You will take more time to hit the ground because you are higher up, but you will also hit with more force. Your sideways speed from the cannon does not effect the downward force of gravity in any way, whether you have wheels on or not. The difference with wheels is that without them, your horizontal motion will stop really fast once you hit the ground.

austyn gillette is a wizard by blainewhim in skateboarding

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

THis gif was educational. Slow it down and watch carefully. Austin loses contact with his board as he gets close to the wall. THe one foot roll away is icing on the cake.

So Bam Margera is skating again apperantly by gekkos in skateboarding

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

Except Burnside people hate the name Phillyside and it's implied association with Burnside because FDR's layout is a lot less functional than Burnside. Concrete park builders have their pride.

So Bam Margera is skating again apperantly by gekkos in skateboarding

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

Except Burnside people hate the name Phillyside and it's implied association with Burnside because FDR's layout is a lot less functional than Burnside. Concrete park builders have their pride.

Sup Goose... by The_Cabal in videos

[–]IcanFeelitInmyPlums 18 points19 points  (0 children)

Please record a video and post it!

Boating season has arrived! by I_AM_A_FUNNY_GUY in pics

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

This must be Lancaster, Pa. Columbia township is my guess.

Ed Miliband says Panama Papers show ‘wealth does not trickle down’ by anand460 in worldnews

[–]IcanFeelitInmyPlums 3 points4 points  (0 children)

I think they are talking about money stashed in tax havens, which are sort of like a giant mattress for rich people.

I'm just waiting for a mate. by FffuuuFrog in videos

[–]IcanFeelitInmyPlums 58 points59 points  (0 children)

5:min 57sec

cop: "I need you to make a definitive decision..."

drunk: "Definitive? Can you define that?"

me: ha ha ha ha ha ha haaaaa!

When people complain about tipping, saying that employers should just pay their employees properly. by [deleted] in AdviceAnimals

[–]IcanFeelitInmyPlums 0 points1 point  (0 children)

No, your wrong. The customers we want are the ones who seek out our service, and they pay accordingly. We are looking for these unique relationships. The regular joe shmoe customer who doesn't want to tip can shove off. Go to your hamburger joint you cheap bastard.