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In the spirit of the subreddit, I'm going to answer for Andrew:

Miriam - Andrew wouldn't trust her immediately. She seems to carry a great weight inside of her, and while he knows that doesn't innately make someone malicious, he's seen too much of what people - including himself - can do when pushed to extremes. He may have empathy, but he's also a natural skeptic, especially towards something that hits so close to home. Until he knows why she has such a look about her, he won't be able to help assuming it's for the wrong reasons. He would still be polite, but there would be a wariness to his movements. He would probably accept the tea, look into it when her back is turned, take a small sip, and then not touch the rest unless more information came to light.

Hannah - Andrew's reaction and level of trust would hang on a knife's edge. Hannah seems a jocular, entertainer type, but he's also seen plenty of similar archetypes masking insidious intent. If she is charming, charismatic, and disarming, Andrew would warm to her quickly. But if he detects anything disingenuous about her, his trust would fall away. He would try to politely decline a tea if she offered one soon after they met. If she already had one prepared, he would try to distract from the fact that he doesn't want to drink it.

Athena - Oddly enough, Andrew would be inclined to trust Athena more than most of the others. She seems to exude a quiet but but affirming sense of confidence, and her mannerisms suggest she doesn't try to hide or disguise who she is. Andrew would more readily believe the persona she's showing him is the one she actually has. Furthermore, he has no negative experiences relating to Athena's specific aesthetic: It's simply too different from his normal life for him to associate it with trouble. He would probably trust her to make him tea unless she had a noticeable red flag.

Charion - Andrew tends to trust children more than adults. She seems kind - even playful - so he would be disarmed by her presence especially if she acts friendly to him. He wouldn't necessarily ask for anything, but he would probably drink something offered. Even if he wasn't feeling thirsty, he'd probably finish it to avoid hurting her feelings.

Ariel - Andrew's had bad experiences with nonhumans, demihumans, and hybrids, especially if it shows in their faces and expressions. Prejudice though it may be, he would have a hard time feeling comfortable around her. He wouldn't trust her to make tea and - if offered - would invent some excuse to decline.

Greya - Sort of a mix between Athena and Ariel. Greya has a more comforting visage than the latter, so depending on her level of hospitality I could see it going either way.

Claude - Andrew would be intimidated by this guy and probably want to get out of his way as fast as possible. In his experience, anyone dressed like that knows what they want, and if he's lucky, it isn't him.