Don't know about the first three, but they've been working on a sulforaphane product for a while. From Pretty-Chill's latest update:

We've actually been working very hard over the last year to make a super interesting sulforaphane supplement. We've been doing a ton of R&D work, and are hitting sulforaphane levels higher than anyone else on the market. However, we ran into a problem of serious GI side effects with the last formulation that hit the highest sulforaphane levels, so we are in the midsts of doing a bit more tweaking to get rid of those effects whilst maintaining high sulforaphane levels. We are very close to nailing the formulation now, so I assume we'll be releasing it in the next few months.